Open Science Research Excellence
@article{(International Science Index):http://waset.org/publications/10002003,
  title    = {Alumina Supported Copper-Manganese Catalysts for Combustion of Exhaust Gases: Catalysts Characterization},
  author    = {Krasimir I. Ivanov and  Elitsa N. Kolentsova and  Dimitar Y. Dimitrov and  Georgi V. Avdeev and  Tatyana T. Tabakova},
  country   = {Bulgaria},
  institution={Agricultural University},
  abstract  = {In recent research copper and manganese systems
were found to be the most active in CO and organic compounds
oxidation among the base catalysts. The mixed copper manganese
oxide has been widely studied in oxidation reactions because of their
higher activity at low temperatures in comparison with single oxide
catalysts. The results showed that the formation of spinel
CuxMn3−xO4 in the oxidized catalyst is responsible for the activity
even at room temperature. That is why the most of the investigations
are focused on the hopcalite catalyst (CuMn2O4) as the best coppermanganese
catalyst. Now it’s known that this is true only for CO
oxidation, but not for mixture of CO and VOCs. The purpose of this
study is to investigate the alumina supported copper-manganese
catalysts with different Cu/Mn molar ratio in terms of oxidation of
CO, methanol and dimethyl ether. The catalysts were prepared by impregnation of γ-Al2O3 with
copper and manganese nitrates and the catalytic activity
measurements were carried out in two stage continuous flow
equipment with an adiabatic reactor for simultaneous oxidation of all
compounds under the conditions closest possible to the industrial. Gas
mixtures on the input and output of the reactor were analyzed with a
gas chromatograph, equipped with FID and TCD detectors. The
texture characteristics were determined by low-temperature (- 196oС)
nitrogen adsorption in a Quantachrome Instruments NOVA 1200e
(USA) specific surface area & pore analyzer. Thermal, XRD and
TPR analyses were performed. It was established that the active component of the mixed Cu-
Mn/γ–alumina catalysts strongly depends on the Cu/Mn molar ratio.
Highly active alumina supported Cu-Mn catalysts for CO, methanol
and DME oxidation were synthesized. While the hopcalite is the best
catalyst for CO oxidation, the best compromise for simultaneous
oxidation of all components is the catalyst with Cu/Mn molar ratio
1:5.},
    journal   = {International Journal of Chemical, Molecular, Nuclear, Materials and Metallurgical Engineering},  volume    = {9},
  number    = {6},
  year      = {2015},
  pages     = {719 - 724},
  ee        = {http://waset.org/publications/10002003},
  url       = {http://waset.org/Publications?p=102},
  bibsource = {http://waset.org/Publications},
  issn      = {eISSN:1307-6892},
  publisher = {World Academy of Science, Engineering and Technology},
  index     = {International Science Index 102, 2015},
}